Literature DB >> 12182612

New and convenient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic organic compounds.

Samia Aït-Mohand1, William R Dolbier.   

Abstract

[reaction: see text] Use of Et3B as a catalytic initiator allows the convenient, regiospecific, and highly stereoselective addition of SF5Cl in high yield to a variety of alkenes and alkynes.

Entities:  

Year:  2002        PMID： 12182612     DOI： 10.1021/ol026483o

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction.

Authors:  George Iakobson; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2012-07-25       Impact factor: 2.883

2.  Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes.

Authors:  George Iakobson; Junyi Du; Alexandra M Z Slawin; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2015-08-26       Impact factor: 2.883

3.  Synthesis and reactivity of aliphatic sulfur pentafluorides from substituted (pentafluorosulfanyl)benzenes.

Authors:  Norbert Vida; Jiří Václavík; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2016-01-20       Impact factor: 2.883

4.  Syn-selective silicon Mukaiyama-type aldol reactions of (pentafluoro-λ6-sulfanyl)acetic acid esters with aldehydes.

Authors:  Anna-Lena Dreier; Andrej V Matsnev; Joseph S Thrasher; Günter Haufe
Journal:  Beilstein J Org Chem       Date:  2018-02-08       Impact factor: 2.883

5.  Amine-borane complex-initiated SF5Cl radical addition on alkenes and alkynes.

Authors:  Audrey Gilbert; Pauline Langowski; Marine Delgado; Laurent Chabaud; Mathieu Pucheault; Jean-François Paquin
Journal:  Beilstein J Org Chem       Date:  2020-12-16       Impact factor: 2.883

Review 6.  (Hetero)aryl-SVI Fluorides: Synthetic Development and Opportunities.

Authors:  Marc Magre; Shengyang Ni; Josep Cornella
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-27       Impact factor: 16.823

Review 7.  Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride.

Authors:  Yannick Kraemer; Emily Nicole Bergman; Antonio Togni; Cody Ross Pitts
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-21       Impact factor: 16.823
  7 in total

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