Literature DB >> 12182565

Ruthenium-catalyzed hydrosilylation of 1-alkynes with novel regioselectivity.

Yukio Kawanami1, Yoshiya Sonoda, Takashi Mori, Keiji Yamamoto.   

Abstract

[reaction: see text] A ruthenium catalyst precursor bearing a bulky and electron-donating pentamethylcyclopentadienyl (Cp) ligand, typically CpRuH3(PPh3), mediates hydrosilylation of several 1-alkynes with novel regioselectivity to give preferentially 2-silyl-1-alkenes.

Entities:  

Year:  2002        PMID： 12182565     DOI： 10.1021/ol026089q

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Sequential Processes in Palladium-Catalyzed Silicon-Based Cross-Coupling.

Authors:  Scott E Denmark; Jack H-C Liu
Journal:  Isr J Chem       Date:  2010-12-07       Impact factor: 3.333

2.  Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.

Authors:  Barry M Trost; Zachary T Ball
Journal:  J Am Chem Soc       Date:  2005-12-21       Impact factor: 15.419

3.  Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes.

Authors:  Wenhao Dai; Xiaowei Wu; Chunpu Li; Rui Zhang; Jiang Wang; Hong Liu
Journal:  RSC Adv       Date:  2018-08-07       Impact factor: 4.036
  3 in total

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