| Literature DB >> 12175199 |
Giuseppe Canepa1, Carsten D Brandt, Helmut Werner.
Abstract
Reaction of HCl with [RhCl(C2H4)(PR3)]2 affords the dinuclear alkylrhodium(III) complex [RhCl2(C2H5)(PR3)]2, the structure of which has been determined crystallographically. PR3 is the formerly unknown trialkyl phosphine tBu2PCH2CH2C6H3-2,6-Me2, prepared in three steps from tBuPCl2. Treatment of the title compound with CO gives the mononuclear rhodium dicarbonyl cis-[RhCl(CO)2(PR3)], being the first fully characterized complex of this type.Entities:
Year: 2002 PMID： 12175199 DOI： 10.1021/ja020560t
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419