Literature DB >> 12170810

2,2-Difluoro-1,3-dimethylimidazolidine (DFI). A new fluorinating agent.

Hidetoshi Hayashi1, Hiroshi Sonoda, Kouki Fukumura, Teruyuki Nagata.   

Abstract

2,2-Difluoro-1,3-dimethylimidazolidine (DFI) is a new deoxo-fluorinating agent that is useful for the conversion of alcohols to monofluorides, and aldehydes/ketones to gemdifluorides under mild conditions.

Entities:  

Year:  2002        PMID： 12170810     DOI： 10.1039/b204471d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Deoxyfluorination of phenols.

Authors:  Pingping Tang; Weike Wang; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2011-07-12       Impact factor: 15.419

2.  Solventless and Metal-free Regioselective Hydrofluorination of Functionalized Alkynes and Allenes: An Efficient Protocol for the Synthesis of gem-Difluorides.

Authors:  Zhichao Lu; Bhvandip S Bajwa; Shiwen Liu; Sheye Lee; Gerald B Hammond; Bo Xu
Journal:  Green Chem       Date:  2019-02-15       Impact factor: 10.182

3.  Iron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion.

Authors:  Deng-Fu Lu; Cheng-Liang Zhu; Jeffrey D Sears; Hao Xu
Journal:  J Am Chem Soc       Date:  2016-08-26       Impact factor: 15.419

4.  Late-stage deoxyfluorination of alcohols with PhenoFluor.

Authors:  Filippo Sladojevich; Sophie I Arlow; Pingping Tang; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2013-02-11       Impact factor: 15.419

5.  Renewable Reagent for Nucleophilic Fluorination.

Authors:  Blaž Alič; Jan Petrovčič; Jan Jelen; Gašper Tavčar; Jernej Iskra
Journal:  J Org Chem       Date:  2022-04-19       Impact factor: 4.198
  5 in total

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