| Literature DB >> 12170783 |
Kazuaki Ishihara1, Yukihiro Hiraiwa, Hisashi Yamamoto.
Abstract
The Me3SiX-induced Mukaiyama aldol reaction proceeds through each catalytic cycle under the influence of X-: the silyl group of Me3SiNTf2 does not release from -NTf2 and that of silyl enol ether intermolecularly transfers to the product, while the silyl group of Me3SiOTf remains in the product and that of the silyl enol ether becomes the catalyst for the next catalytic cycle.Entities:
Year: 2002 PMID： 12170783 DOI： 10.1039/b203838b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222