Literature DB >> 12167011

Dimerization of the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] via mercurophilic interactions.

Julie B King1, Mason R Haneline, Mitsukimi Tsunoda, François P Gabbaï.   

Abstract

In the crystalline state, the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] forms cofacial dimers which are held by two mercurophilic interactions of 3.51 A. In this form, the complex displays an intense photoluminescence with a sharp emission centered at 480 nm.

Entities:  

Year:  2002        PMID： 12167011     DOI： 10.1021/ja0268534

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Chlorido(2-formyl-6-hydroxy-phenyl-κC)mercury(II).

Authors:  Chen Xu; Fei-Fei Cen; Zhi-Qiang Wang; Yu-Qing Zhang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-06-10

2.  Tenfold Metalation of Ferrocene: Synthesis, Structures, and Metallophilic Interactions in FeC10 (HgX)10.

Authors:  Susanne Margot Rupf; Gabriel Schröder; Robin Sievers; Moritz Malischewski
Journal:  Chemistry       Date:  2021-02-22       Impact factor: 5.236

3.  Crystal structure of {2,6-bis-[(di-methyl-amino)-meth-yl]phenyl-κ3N,C1,N'}(bromido/chlorido)-mercury(II).

Authors:  Anand Gupta; Harkesh B Singh; Ray J Butcher
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-10-20
  3 in total

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