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Literature DB >> 12154317

(1S,3R,8S,9S,10R)-2,2-Dichloro-9,10-epoxy-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecane and (1S,3R,8S,10R)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecan-9-one.

F Sbai¹, M Dakir, A Auhmani, H El Jamili, M Akssira, A Benharref, A Kenz, M Pierrot.

Abstract

The stereochemistries of the title compounds, both C(16)H(24)Cl(2)O, have been established by X-ray diffraction. In both structures, the seven-membered ring adopts the same conformation, whereas the six-membered ring shows an envelope conformation in the epoxydodecane structure and a boat conformation in the dodecan-9-one structure.

Entities: Chemical

Mesh：

Substances：

Year: 2002 PMID： 12154317 DOI： 10.1107/s0108270102012283

Source DB: PubMed Journal: Acta Crystallogr C ISSN： 0108-2701 Impact factor: 1.172

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Cited

13 in total

1. (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra-methyl-9,10-ep-oxy-tricyclo-[6.4.0.0]dodeca-ne.

Authors: Ahmed Benharref; Lahcen El Ammari; Daniel Avignant; Abdelghani Oudahmane; Moha Berraho
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2010-11-10

2. (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra-methyl-tricyclo-[5.5.0.0]dodeca-6,8-diene.

Authors: Ahmed Benharref; Lahcen El Ammari; Moha Berraho; Esaadia Lassaba
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2010-08-28

3. (1S,2R,8R)-2,2-Dichloro-3,7,7,10-tetra-methyltricyclo-[6.4.0.0]dodec-10-en-9-one.

Authors: Ahmed Benharref; Lahcen El Ammari; Moha Berraho
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2010-10-23

4. (1S,3R,8R,11S)-2,2-Dichloro-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0]dodec-9-en-11-ol.

Authors: Ahmed Benharref; Essêdiya Lassaba; Daniel Avignant; Abdelghani Oudahmane; Moha Berraho
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2011-02-12

5. (1S,3R,8R)-2,2-Dibromo-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0(1,3)]dodec-9-ene.

Authors: Ahmed Benharref; Lahcen El Ammari; Essêdiya Lassaba; Najia Ourhriss; Moha Berraho
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2012-07-21

6. (1S,3R,8R,9R,10S)-2,2-Dibromo-3,7,7,10-tetra-methyl-9β,10β-ep-oxy-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0(1,3)]dodeca-ne.

Authors: Abdelouahd Oukhrib; Ahmed Benharref; Mohamed Saadi; Moha Berraho; Lahcen El Ammari
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2013-03-09

(1S,3R,8S,9S,10R)-2,2-Dichloro-9,10-epoxy-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecane and (1S,3R,8S,10R)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecan-9-one.

1. (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra-methyl-9,10-ep-oxy-tricyclo-[6.4.0.0]dodeca-ne.

2. (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra-methyl-tricyclo-[5.5.0.0]dodeca-6,8-diene.

3. (1S,2R,8R)-2,2-Dichloro-3,7,7,10-tetra-methyltricyclo-[6.4.0.0]dodec-10-en-9-one.

4. (1S,3R,8R,11S)-2,2-Dichloro-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0]dodec-9-en-11-ol.

5. (1S,3R,8R)-2,2-Dibromo-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0(1,3)]dodec-9-ene.

6. (1S,3R,8R,9R,10S)-2,2-Dibromo-3,7,7,10-tetra-methyl-9β,10β-ep-oxy-3,7,7,10-tetra-methyl-tricyclo-[6.4.0.0(1,3)]dodeca-ne.

7. (1S,3R,8R)-2,2-Dibromo-10-bromo-methyl-3,7,7-trimethyl-tricyclo-[6.4.0.0(1,3)]dodec-9-ene.

8. 2,2-Dichloro-3,7,7,11-tetra-methyl-10-aza-tetra-cyclo-[6.5.0.0(1,3).0(9,11)]trideca-ne.

9. (1S,3R,8R)-2,2-Dibromo-3,7,7,10-tetra-methyltricyclo-[6.4.0.0(1,3)]dodec-9-en-11-one.

10. (1S,3R,8R,9S,11R)-2,2,10,10-Tetra-chloro-3,7,7,11-tetra-methyl-tetra-cyclo-[6.5.0.0(1,3).0(9,11)]trideca-ne.