Literature DB >> 12153224

Catalytic diastereoselective reductive claisen rearrangement.

Steven P Miller1, James P Morken.   

Abstract

[reaction: see text] A catalytic amount of [(cod)RhCl](2) and MeDuPhos initiates an ester enolate Claisen rearrangement with good yields and diastereocontrol. Reaction conditions are mild and tolerant of base-sensitive functionality.

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Year:  2002        PMID: 12153224     DOI: 10.1021/ol026273b

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Synthesis of gamma,delta-unsaturated glycolic acids via sequenced brook and Ireland--claisen rearrangements.

Authors:  Daniel C Schmitt; Jeffrey S Johnson
Journal:  Org Lett       Date:  2010-03-05       Impact factor: 6.005

  1 in total

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