Literature DB >> 12148997

Excited-state proton transfer in chiral environments. 1. Chiral solvents.

Kyril M Solntsev1, Laren M Tolbert, Boiko Cohen, Dan Huppert, Yoshihito Hayashi, Yuri Feldman.   

Abstract

Excited-state proton transfer from the "super" photoacid 5,8-dicyano-2-naphthol to 2-butanol is faster in the enantiopure solvent than in its racemic form. The difference observed is discussed in terms of long-range order in homo- and heterodimers of 2-butanol.

Entities:  

Year:  2002        PMID： 12148997     DOI： 10.1021/ja026896k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Intramolecular Relaxation Dynamics Mediated by Solvent-Solute Interactions of Substituted Fluorene Derivatives. Solute Structural Dependence.

Authors:  Briana A Capistran; Stephen H Yuwono; Mehdi Moemeni; Soham Maity; Aria Vahdani; Babak Borhan; James E Jackson; Piotr Piecuch; Marcos Dantus; G J Blanchard
Journal:  J Phys Chem B       Date:  2021-11-09       Impact factor: 3.466

2.  Excited-State Proton Transfer in Chiral Environments: Photoracemization of BINOLs.

Authors:  Kyril M Solntsev; Elizabeth-Ann Bartolo; George Pan; Gilles Muller; Shruthi Bommireddy; Dan Huppert; Laren M Tolbert
Journal:  Isr J Chem       Date:  2009       Impact factor: 3.333
  2 in total

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