Literature DB >> 12137507

Is the axial zero-field splitting parameter of tetragonally elongated high-spin manganese(III) complexes always negative?

Susanne Mossin1, Høgni Weihe, Anne-Laure Barra.   

Abstract

The positive axial zero-field splitting parameter D relevant for the S = 2 ground state of [Mn(cyclam)I2]I (cyclam = 1,4,8,11-tetraazacyclotetradecane) is interpreted using the valence bond configuration interaction model which explicitly considers the covalency of the manganese-iodide bond.

Entities:  

Year:  2002        PMID： 12137507     DOI： 10.1021/ja012574p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

Review 1.  High-frequency and high-field electron paramagnetic resonance (HFEPR): a new spectroscopic tool for bioinorganic chemistry.

Authors:  Joshua Telser; J Krzystek; Andrew Ozarowski
Journal:  J Biol Inorg Chem       Date:  2014-01-30       Impact factor: 3.358

2.  Mn(III) species formed by the multi-copper oxidase MnxG investigated by electron paramagnetic resonance spectroscopy.

Authors:  Lizhi Tao; Troy A Stich; Alexandra V Soldatova; Bradley M Tebo; Thomas G Spiro; William H Casey; R David Britt
Journal:  J Biol Inorg Chem       Date:  2018-07-02       Impact factor: 3.358

3.  Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes.

Authors:  Lianke Wang; Matija Zlatar; Filip Vlahović; Serhiy Demeshko; Christian Philouze; Florian Molton; Marcello Gennari; Franc Meyer; Carole Duboc; Maja Gruden
Journal:  Chemistry       Date:  2018-03-02       Impact factor: 5.236

4.  The Origin of Magnetic Anisotropy and Single-Molecule Magnet Behavior in Chromium(II)-Based Extended Metal Atom Chains.

Authors:  Andrea Cornia; Anne-Laure Barra; Vladimir Bulicanu; Rodolphe Clérac; Miguel Cortijo; Elizabeth A Hillard; Rita Galavotti; Alessandro Lunghi; Alessio Nicolini; Mathieu Rouzières; Lorenzo Sorace; Federico Totti
Journal:  Inorg Chem       Date:  2020-01-22       Impact factor: 5.165
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.