Literature DB >> 12132484

Synthesis and structural characterisation of stable pyridine- and phosphine-functionalised N-heterocyclic carbenes.

Andreas A Danopoulos1, Scott Winston, Thomas Gelbrich, Michael B Hursthouse, Robert P Tooze.   

Abstract

Stable, uncoordinated (1-[2-(6-trimethylsilyl)pyridyl]-3-[(2,6- diisopropyl)phenyl]imidazol-2-ylidene), I, and (1-[beta-(diphenylphosphino)ethyl]-3-[(2,6-diisopropyl)phenyl]imidazol- 2-ylidene), II, have been synthesised; in the solid state they adopt a conformation with the lone pairs in a mutually anti arrangement.

Entities:  

Year:  2002        PMID: 12132484     DOI: 10.1039/b111659b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  1,3-Bis[(3-allyl-imidazol-3-ium-1-yl)meth-yl]benzene bis-(hexa-fluoridophosphate).

Authors:  Rosenani A Haque; Mohammed Z Ghdhayeb; Hassan H Abdallah; Ching Kheng Quah; Hoong-Kun Fun
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-12-11
  1 in total

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