Literature DB >> 12123376

Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts.

Vincenzo Caló1, Angelo Nacci, Antonio Monopoli, Antonello Fanizzi.   

Abstract

[reaction: see text] Epoxides dissolved in molten tetralkylammonium salts bearing halides as counterions are converted into cyclic carbonates under atmospheric pressure of carbon dioxide. The reaction rate depends on the nucleophilicity of the halide ion as well as the structure of the cation.

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Year:  2002        PMID: 12123376     DOI: 10.1021/ol026189w

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  12 in total

1.  Theoretical investigation of the mechanism for the cycloaddition of CO2 to epoxides catalyzed by a magnesium(II) porphyrin complex.

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Journal:  Chem Sci       Date:  2022-03-15       Impact factor: 9.969

3.  Cu/TEMPO catalyzed dehydrogenative 1,3-dipolar cycloaddition in the synthesis of spirooxindoles as potential antidiabetic agents.

Authors:  Chitrala Teja; Spoorthy N Babu; Ayesha Noor; J Arul Daniel; S Asha Devi; Fazlur Rahman Nawaz Khan
Journal:  RSC Adv       Date:  2020-03-25       Impact factor: 4.036

4.  2,2',2''-Terpyridine-catalyzed synthesis of cyclic carbonates from epoxides and carbon dioxide under solvent-free conditions.

Authors:  Huixin Liu; Renqin Zeng; Ruimao Hua
Journal:  Int J Mol Sci       Date:  2014-06-04       Impact factor: 5.923

5.  CO2 Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System.

Authors:  Maximilian Tiffner; Sabrina Gonglach; Michael Haas; Wolfgang Schöfberger; Mario Waser
Journal:  Chem Asian J       Date:  2017-04-20

6.  Highly efficient Co centers functionalized by nitrogen-doped carbon for the chemical fixation of CO2.

Authors:  Yuying Yang; Hong Li; Supeng Pei; Feng Liu; Wei Feng; Yongming Zhang
Journal:  RSC Adv       Date:  2020-11-23       Impact factor: 4.036

7.  Mechanism of cyclic carbonate synthesis from epoxides and CO2.

Authors:  Michael North; Riccardo Pasquale
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

8.  Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization.

Authors:  Benjamin R Buckley; Anish P Patel; K G Upul Wijayantha
Journal:  European J Org Chem       Date:  2014-12-10

9.  Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer.

Authors:  Yong Xie; Ting-Ting Wang; Xiao-Huan Liu; Kun Zou; Wei-Qiao Deng
Journal:  Nat Commun       Date:  2013       Impact factor: 14.919

10.  Comparing kinetic profiles between bifunctional and binary type of Zn(salen)-based catalysts for organic carbonate formation.

Authors:  Carmen Martín; Arjan W Kleij
Journal:  Beilstein J Org Chem       Date:  2014-08-08       Impact factor: 2.883

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