Literature DB >> 12123081

Chiral induction controlled by aggregation of organometallics: trifluoromethylated aminoalcohols for chiral ligands in Et2Zn alkylation of benzaldehyde.

Toshimasa Katagiri1, Yasuyuki Fujiwara, Satoshi Takahashi, Nobuyuki Ozaki, Kenji Uneyama.   

Abstract

Chiral induction in the reaction of Et2Zn with PhCHO by fluorinated chiral amino alcohols was correlated to the extent of aggregation of Et2Zn species, which was estimated by manometric study.

Entities:  

Year:  2002        PMID： 12123081     DOI： 10.1039/b201238c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Synthesis of β-amino-α-trifluoromethyl alcohols and their applications in organic synthesis.

Authors:  Grzegorz Mlostoń; Emilia Obijalska; Heinz Heimgartner
Journal:  J Fluor Chem       Date:  2010-06-04       Impact factor: 2.050
  1 in total

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