| Literature DB >> 12123036 |
Justin K Brask1, Víctor Durà-Vilà, Paula L Diaconescu, Christopher C Cummins.
Abstract
A dramatic difference in behavior is observed for the dithiocarbamate and carbamate complexes [Ar(But)N]3V(NCE2)Na(THF)2(E = S or O, respectively), prepared from the corresponding nitride species ([Ar(But)N]3V identical to NNa)2 by way of a nucleophilic addition reaction involving carbon disulfide or dioxide, and is rationalized with the aid of DFT calculations.Entities:
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Year: 2002 PMID： 12123036 DOI： 10.1039/b111550m
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222