Literature DB >> 12120146

A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide pi-donor ancillary ligand.

Winfried P Kretschmer1, Chris Dijkhuis, Auke Meetsma, Bart Hessen, Jan H Teuben.   

Abstract

The titanium complex Cp[1,3-(2',6'-Me2C6H3)2(CH2N)2C=N]Ti(CH2Ph)2, with a monoanionic eta 1-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)3.

Entities:  

Year:  2002        PMID: 12120146     DOI: 10.1039/b111343g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Effect of para-Substituents in Ethylene Copolymerizations with 1-Decene, 1-Dodecene, and with 2-Methyl-1-Pentene Using Phenoxide Modified Half-Titanocenes-MAO Catalyst Systems.

Authors:  Suphitchaya Kitphaitun; Qing Yan; Kotohiro Nomura
Journal:  ChemistryOpen       Date:  2021-07-05       Impact factor: 2.630

  1 in total

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