Literature DB >> 12120082

Hydride encapsulation in s-block metal inverse crown chemistry.

Daniel J Gallagher1, Kenneth W Henderson, Alan R Kennedy, Charles T O'Hara, Robert E Mulvey, René B Rowlings.   

Abstract

A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2(N(Pri)2)4(mu-H)2.(toluene)2], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.

Entities:  

Year:  2002        PMID: 12120082     DOI: 10.1039/b110117j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

Authors:  Victoria L Blair; William Clegg; Ben Conway; Eva Hevia; Alan Kennedy; Jan Klett; Robert E Mulvey; Luca Russo
Journal:  Chemistry       Date:  2008       Impact factor: 5.236

  1 in total

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