Literature DB >> 12119713

Synthesis of a highly enantiomerically enriched silyllithium compound.

Carsten Strohmann1, Jan Hörnig, Dominik Auer.   

Abstract

The highly enantiomerically enriched silyllithium compound lithiomethylphenyl(1-piperidinylmethyl)silane (4) reacts stereospecifically with chlorosilanes, but over a period of several hours slow racemization in solution at room temperature occurs, which can be suppressed by a transmetalation reaction with MgBr2(thf)4.

Entities:  

Year:  2002        PMID： 12119713     DOI： 10.1039/b111687h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  (S)-1,2-Dimethyl-1,1,2-triphenyl-2-(4-piperidiniometh-yl)disilane chloride.

Authors:  Christian Däschlein; Viktoria H Gessner; Carsten Strohmann
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-17

2.  Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones.

Authors:  Ryo Shintani; Ryo Takano; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-09       Impact factor: 9.825

3.  Isolation and Versatile Derivatization of an Unsaturated Anionic Silicon Cluster (Siliconoid).

Authors:  Philipp Willmes; Kinga Leszczyńska; Yannic Heider; Kai Abersfelder; Michael Zimmer; Volker Huch; David Scheschkewitz
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-22       Impact factor: 15.336
  3 in total

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