Literature DB >> 12119676

A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects.

Francesco Minisci1, Carlo Punta, Francesco Recupero, Francesca Fontana, Gian Franco Pedulli.   

Abstract

A new selective synthesis of aromatic aldehydes is described, based on catalytic oxidation of benzyl alcohols with molecular oxygen at rt and atmospheric pressure.

Entities:  

Year:  2002        PMID： 12119676     DOI： 10.1039/b110451a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Electrochemical alcohols oxidation mediated by N-hydroxyphthalimide on nickel foam surface.

Authors:  Leila Behrouzi; Robabeh Bagheri; Mohammad Reza Mohammadi; Zhenlun Song; Petko Chernev; Holger Dau; Mohammad Mahdi Najafpour; Babak Kaboudin
Journal:  Sci Rep       Date:  2020-11-09       Impact factor: 4.379

2.  Oxyfunctionalization of Benzylic C-H Bonds of Toluene Mediated by Covalently Anchored Co-Schiff Bases.

Authors:  Guojun Shi; Yuxin Liang; Hongyu Zhou; Zhengliang Zhao; Wenjie Yang
Journal:  Molecules       Date:  2022-08-19       Impact factor: 4.927

3.  Metal-free aerobic oxidations mediated by N-hydroxyphthalimide. A concise review.

Authors:  Lucio Melone; Carlo Punta
Journal:  Beilstein J Org Chem       Date:  2013-07-02       Impact factor: 2.883

4.  Direct α-heteroarylation of amides (α to nitrogen) and ethers through a benzaldehyde-mediated photoredox reaction.

Authors:  Yongqiang Zhang; Kevin B Teuscher; Haitao Ji
Journal:  Chem Sci       Date:  2015-12-07       Impact factor: 9.825
  4 in total

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