Literature DB >> 12109076

First successful reaction of a silyl anion with hafnium tetrachloride.

Dieter Frank1, Judith Baumgartner, Christoph Marschner.   

Abstract

Hafnium tetrachloride reacts with the tris(trimethylsilyl)silyl potassium tmen adduct (1) to form a [tris(trimethylsilyl)silyl]trichlorohafnium tmen complex (2); reaction of 2 with 2,6-dimethylphenylisonitrile leads to insertion into the silicon hafnium bond (4).

Entities:  

Year:  2002        PMID： 12109076     DOI： 10.1039/b201508k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Neutral "Cp-Free" Silyl-Lanthanide(II) Complexes: Synthesis, Structure, and Bonding Analysis.

Authors:  Rainer Zitz; Johann Hlina; Karl Gatterer; Christoph Marschner; Tibor Szilvási; Judith Baumgartner
Journal:  Inorg Chem       Date:  2015-07-01       Impact factor: 5.165

2.  Using Functionalized Silyl Ligands To Suppress Solvent Coordination to Silyl Lanthanide(II) Complexes.

Authors:  Rainer Zitz; Johann Hlina; Mohammad Aghazadeh Meshgi; Heinz Krenn; Christoph Marschner; Tibor Szilvási; Judith Baumgartner
Journal:  Inorg Chem       Date:  2017-04-11       Impact factor: 5.165

3.  Hypercoordinated Oligosilanes Based on Aminotrisphenols.

Authors:  Mohammad Aghazadeh Meshgi; Kirill V Zaitsev; Mikhail V Vener; Andrei V Churakov; Judith Baumgartner; Christoph Marschner
Journal:  ACS Omega       Date:  2018-08-31
  3 in total

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