Literature DB >> 12109069

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides.

Katy J Drewette1, Kenneth W Henderson, Alan R Kennedy, Robert E Mulvey, Charles T O'Hara, René B Rowlings.   

Abstract

A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [(MMg[N(Pri)2]2OR)2] (where M = Li, R = Octn; M = Na, R = Bun or Octn), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

Entities:  

Year:  2002        PMID： 12109069     DOI： 10.1039/b202549c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

Authors:  Victoria L Blair; William Clegg; Ben Conway; Eva Hevia; Alan Kennedy; Jan Klett; Robert E Mulvey; Luca Russo
Journal:  Chemistry       Date:  2008       Impact factor: 5.236

2.  Assessing Alkali-Metal Effects in the Structures and Reactivity of Mixed-Ligand Alkyl/Alkoxide Alkali-Metal Magnesiates.

Authors:  Neil R Judge; Leonie J Bole; Eva Hevia
Journal:  Chemistry       Date:  2022-01-27       Impact factor: 5.020
  2 in total

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