| Literature DB >> 12108981 |
Abstract
Chemical reactions are at the heart of chemistry and the dream of controlling the outcome of these reactions is an old one. Thus, with given reactants, a solvent and perhaps assisted by a catalyst, we would like to 'steer' the reactants into a particular desired product. This review focuses on how to control the dynamics of chemical reactions, beyond traditional temperature control, with the emphasis on unimolecular reactions. The electromagnetic radiation of lasers can induce so-called coherent dynamics. The recent theoretical and experimental results on this coherent control are explained and illustrated with computational and experimental examples.Year: 2002 PMID: 12108981 DOI: 10.1039/b100111f
Source DB: PubMed Journal: Chem Soc Rev ISSN: 0306-0012 Impact factor: 54.564