Literature DB >> 12098228

Palladium-catalyzed homocoupling reactions between two Csp(3)-Csp(3) centers.

Aiwen Lei1, Xumu Zhang.   

Abstract

[reaction: see text] A novel palladium-catalyzed coupling reaction between two Csp(3)-Csp(3) centers has been investigated. This protocol is initiated by the oxidative addition of an alpha-halo carbonyl compound to a palladium(0) species, followed by the double transmetalation. The key dialkyl palladium intermediate undergoes reductive elimination to form the desired coupling product.

Entities:  

Year:  2002        PMID： 12098228     DOI： 10.1021/ol0258536

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents.

Authors:  Matteo Chierchia; Peilin Xu; Gabriel J Lovinger; James P Morken
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-28       Impact factor: 15.336

2.  C(sp3)-C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine.

Authors:  Dawei Cao; Chen-Chen Li; Huiying Zeng; Yong Peng; Chao-Jun Li
Journal:  Nat Commun       Date:  2021-06-17       Impact factor: 14.919
  2 in total

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