Literature DB >> 12094029

(Dibenzyl sulfoxide-kappa O)bis(1,3-diphenylpropane-1,3-dionato-kappa(2)O,O')dioxouranium(VI).

Hoong-Kun Fun1, S Kannan, Anwar Usman, Ibrahim Abdul-Razak, Suchada Chantrapromma.   

Abstract

In the title compound, [UO(2)(C(15)H(11)O(2))(2)(C(14)H(14)OS)], the U(VI) atom is coordinated by seven O atoms in a distorted pentagonal-bipyramidal geometry. Both diphenylpropane-1,3-dionate systems are nearly planar. The sulfoxide moiety is in a distorted tetrahedral geometry, while its two aromatic rings are nearly orthogonal to one another. The crystal packing is stabilized by two bifurcated hydrogen-bonding interactions involving both uranyl O atoms.

Entities:  

Year:  2002        PMID: 12094029     DOI: 10.1107/s010827010200848x

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Bis(2-benzoyl-1-phenyl-ethenolato-κO,O')(ethanol-κO)dioxidouranium(VI).

Authors:  Koichiro Takao; Yasuhisa Ikeda
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2007-12-18
  1 in total

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