Literature DB >> 1208098

The mechanisms of amino acids synthesis by high temperature shock-waves.

I Barak, A Bar-Nun.   

Abstract

The mechanisms of amino acids synthesis behind high temperature shock-waves were elucidated and distinction was made between the steps occurring in the gas phase and those occurring in solution. In the presence of water vapor, aldehydes and HCN are formed separately in regions of different temperatures along the reacting gas. The aldehydes and ammonia condense to aldimines which add HCN to form alpha-amino nitriles, all in the gas phase. The hydrolysis to amino acids takes place in solution. In the absence of water vapor, aldimines and HCN are formed in the gas phase but condense to alpha-amino nitriles only in solution. A fair amount of oxygen only lowers the production of amino acids, which consequently could be still produced in the presence of oxygen in the Earth's primitive atmoshere. The waterless mechanism can operate in the Jovian atmosphere and supply it with ample amounts of amino acids, especially aspartic.

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Year:  1975        PMID: 1208098     DOI: 10.1007/bf00928897

Source DB:  PubMed          Journal:  Orig Life        ISSN: 0302-1688


  5 in total

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Authors:  S L MILLER
Journal:  Biochim Biophys Acta       Date:  1957-03

2.  'Thunder': shock waves in pre-biological organic synthesis.

Authors:  A Bar-Nun; M E Tauber
Journal:  Space Life Sci       Date:  1972-06

3.  Shock synthesis of amino acids in simulated primitive environments.

Authors:  A Bar-Nun; N Bar-Nun; S H Bauer; C Sagan
Journal:  Science       Date:  1970-04-24       Impact factor: 47.728

4.  Cyanoacetylene in prebiotic synthesis.

Authors:  R A Sanchez; J P Ferris; L E Orgel
Journal:  Science       Date:  1966-11-11       Impact factor: 47.728

5.  Alpha-aminonitriles formed by an electric discharge through a mixture of anhydrous methane and ammonia.

Authors:  C Ponnamperuma; F Woeller
Journal:  Curr Mod Biol       Date:  1967-05
  5 in total
  6 in total

1.  The spark discharge synthesis of amino acids from various hydrocarbons.

Authors:  D Ring; S L Miller
Journal:  Orig Life Evol Biosph       Date:  1984       Impact factor: 1.950

2.  Inadequacy of prebiotic synthesis as origin of proteinous amino acids.

Authors:  J T Wong; P M Bronskill
Journal:  J Mol Evol       Date:  1979-07-18       Impact factor: 2.395

3.  Experimental shock chemistry of aqueous amino acid solutions and the cometary delivery of prebiotic compounds.

Authors:  J G Blank; G H Miller; M J Ahrens; R E Winans
Journal:  Orig Life Evol Biosph       Date:  2001 Feb-Apr       Impact factor: 1.950

4.  Prebiotic chemistry in clouds.

Authors:  V R Oberbeck; J Marshall; T Shen
Journal:  J Mol Evol       Date:  1991       Impact factor: 2.395

5.  Carbon and energy yields in prebiotic syntheses using atmospheres containing CH4, CO and CO2.

Authors:  S L Miller; G Schlesinger
Journal:  Orig Life       Date:  1984

6.  A study of the interaction of glycine and its oligohomopeptides with formaldehyde and acetaldehyde under possible primitive earth conditions.

Authors:  C P Ivanov; O C Ivanov
Journal:  Orig Life       Date:  1983-12
  6 in total

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