Literature DB >> 12059184

Stable (amino)(phosphino)carbenes: difunctional molecules.

Nathalie Merceron1, Karinne Miqueu, Antoine Baceiredo, Guy Bertrand.   

Abstract

(Amino)(phosphino)carbenes are stable due to the donation of the nitrogen lone pair, the phosphino group remains strongly pyramidalized. Reactions can be performed selectively at the carbene center, but also at the phosphorus center leading to new stable carbenes. These difunctional molecules can be considered as hybrid ligands.

Entities:  

Year:  2002        PMID： 12059184     DOI： 10.1021/ja026556z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  A Brief Survey of our Contribution to Stable Carbene Chemistry.

Authors:  David Martin; Mohand Melaimi; Michele Soleilhavoup; Guy Bertrand
Journal:  Organometallics       Date:  2011-09-22       Impact factor: 3.876

Review 2.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

3.  CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.

Authors:  Julien Monot; Louis Fensterbank; Max Malacria; Emmanuel Lacôte; Steven J Geib; Dennis P Curran
Journal:  Beilstein J Org Chem       Date:  2010-08-02       Impact factor: 2.883

4.  A persistent P,N-heterocyclic carbene.

Authors:  Guido D Frey; Maoying Song; Jean-Baptiste Bourg; Bruno Donnadieu; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Commun (Camb)       Date:  2008-09-05       Impact factor: 6.222

5.  New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines.

Authors:  Salvador Conejero; Maoying Song; David Martin; Yves Canac; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Asian J       Date:  2006-07-17

6.  A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity.

Authors:  Emmanuelle Teuma; Céline Lyon-Saunier; Heinz Gornitzka; Gérard Mignani; Antoine Baceiredo; Guy Bertrand
Journal:  J Organomet Chem       Date:  2005       Impact factor: 2.369

7.  On the Coexistence of the Carbene⋯H-D Hydrogen Bond and Other Accompanying Interactions in Forty Dimers of N-Heterocyclic-Carbenes (I, IMe2, IiPr2, ItBu2, IMes2, IDipp2, IAd2; I = imidazol-2-ylidene) and Some Fundamental Proton Donors (HF, HCN, H2O, MeOH, NH3).

Authors:  Mirosław Jabłoński
Journal:  Molecules       Date:  2022-09-05       Impact factor: 4.927
  7 in total

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