Literature DB >> 12027628

Rhodium(I)-catalyzed silylation of aryl halides with triethoxysilane: practical synthetic route to aryltriethoxysilanes.

Miki Murata1, Masanori Ishikura, Masayuki Nagata, Shinji Watanabe, Yuzuru Masuda.   

Abstract

[reaction: see text] The specific silylation of aryl iodides and bromides with triethoxysilane (EtO)(3)SiH in the presence of NEt(3) and a catalytic amount of [Rh(cod)(MeCN)(2)]BF(4) provides the corresponding aryltriethoxysilanes in high yield.

Entities:  

Year:  2002        PMID： 12027628     DOI： 10.1021/ol025770p

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

Authors:  Bo Su; Tai-Gang Zhou; Xian-Wei Li; Xiao-Ru Shao; Pei-Lin Xu; Wen-Lian Wu; John F Hartwig; Zhang-Jie Shi
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-15       Impact factor: 15.336

2.  Silver-mediated fluorination of aryl silanes.

Authors:  Pingping Tang; Tobias Ritter
Journal:  Tetrahedron       Date:  2011-06-17       Impact factor: 2.457

Review 3.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

4.  The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.

Authors:  Chunhui Huang; Natalia Chernyak; Alexander S Dudnik; Vladimir Gevorgyan
Journal:  Adv Synth Catal       Date:  2011-05-01       Impact factor: 5.837

5.  A well-defined NHC-Ir(iii) catalyst for the silylation of aromatic C-H bonds: substrate survey and mechanistic insights.

Authors:  Laura Rubio-Pérez; Manuel Iglesias; Julen Munárriz; Victor Polo; Vincenzo Passarelli; Jesús J Pérez-Torrente; Luis A Oro
Journal:  Chem Sci       Date:  2017-04-05       Impact factor: 9.825

6.  Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.

Authors:  Tatsuki Nagata; Takeru Inoue; Xianjin Lin; Shinya Ishimoto; Seiya Nakamichi; Hideo Oka; Ryota Kondo; Takeyuki Suzuki; Yasushi Obora
Journal:  RSC Adv       Date:  2019-06-03       Impact factor: 4.036

7.  The synthesis of 1-(4-triethoxysilyl)phenyl)-4,4,4-trifluoro-1,3-butanedione, a novel trialkoxysilane monomer for the preparation of functionalized sol-gel matrix materials.

Authors:  Christopher J Peeples; Raghu Ram Earni; John C DiCesare
Journal:  Molecules       Date:  2008-10-20       Impact factor: 4.411
  7 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.