| Literature DB >> 12020165 |
Phyllis A Leber1, John E Baldwin.
Abstract
Stereochemical, kinetic, and theory-based studies of the [1,3] carbon sigmatropic rearrangements of bicyclo[2.1.1]hex-2-enes, bicyclo[3.2.0]hept-2-enes, and monocyclic vinylcyclobutanes support the judgment that such reactions involve transient diradical structures traversing relatively flat potential energy surfaces.Entities:
Year: 2002 PMID： 12020165 DOI： 10.1021/ar010100p
Source DB: PubMed Journal: Acc Chem Res ISSN： 0001-4842 Impact factor: 22.384