| Literature DB >> 12010021 |
Ronny Priefer1, Yoon Joo Lee, Fabiola Barrios, Jordan H Wosnick, Anne-Marie Lebuis, Patrick G Farrell, David N Harpp, Aiming Sun, Shaoxiong Wu, James P Snyder.
Abstract
Dicubyl disulfide (1) has been prepared in six steps from commercially available dimethyl-1,4-cubanedicarboxylate in 47% overall yield. In the final step, the previously unknown cubanethiol 2 was oxidized to disulfide 1. X-ray crystallography for 1 reveals the shortest tetragonal C-S bond on record (1.771 A). In contrast to previous generalizations, density functional theory calculations predict a low S-S rotation barrier similar to that for t-BuSSBu-t. Low-temperature (13)C NMR (600 MHz) confirms the prediction.Entities:
Year: 2002 PMID： 12010021 DOI： 10.1021/ja025823y
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419