Literature DB >> 12005698

Universality class of criticality in the restricted primitive model electrolyte.

Erik Luijten1, Michael E Fisher, Athanassios Z Panagiotopoulos.   

Abstract

The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using loci in the temperature-density or (T,rho) plane of isothermal rho(2-k) vs pressure inflections, of Q identical with<m(2)>(2)/<m(4)> maxima, and of canonical and C(V) criticality, yield estimates of (T(c),rho(c)) to +/-(0.04,3)%. Extrapolated exponents and Q ratio are (gamma,nu,Q(c)) = [1.24(3), 0.63(3); 0.624(2)], which support Ising (n = 1) behavior with (1.23(9), 0.630(3); 0.623(6)), but exclude classical, XY (n = 2), self-avoiding walk (n = 0), and n = 1 criticality with potentials varphi(r)>Phi/r(4.9) when r-->infinity.

Entities:  

Year:  2002        PMID: 12005698     DOI: 10.1103/PhysRevLett.88.185701

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  2 in total

1.  Molecular multivalent electrolytes: microstructure and screening lengths.

Authors:  P González-Mozuelos; M S Yeom; M Olvera de la Cruz
Journal:  Eur Phys J E Soft Matter       Date:  2005-02-22       Impact factor: 1.890

2.  Improving the efficiency of Monte Carlo simulations of ions using expanded grand canonical ensembles.

Authors:  Harold W Hatch; Steven W Hall; Jeffrey R Errington; Vincent K Shen
Journal:  J Chem Phys       Date:  2019-10-14       Impact factor: 3.488

  2 in total

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