Literature DB >> 11975615

TEMPO-catalyzed aerobic oxidation of alcohols to aldehydes and ketones in ionic liquid [bmim][PF6].

Imtiaz A Ansari1, Rene Gree.   

Abstract

[reaction: see text]. A simple and mild TEMPO-CuCl catalyzed aerobic oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones in ionic liquid [bmim][PF6] with no trace of overoxidation to carboxylic acids has been developed. The product can be isolated by a simple extraction with organic solvent, and the ionic liquid can be recycled or reused.

Entities:  

Year:  2002        PMID： 11975615     DOI： 10.1021/ol025721c

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  9 in total

Review 1.  Aerobic copper-catalyzed organic reactions.

Authors:  Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal:  Chem Rev       Date:  2013-06-20       Impact factor: 60.622

2.  Highly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.

Authors:  Yingguang Zhu; Baoguo Zhao; Yian Shi
Journal:  Org Lett       Date:  2013-02-15       Impact factor: 6.005

Review 3.  Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems.

Authors:  Bradford L Ryland; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

4.  Development and comparison of the substrate scope of Pd-catalysts for the aerobic oxidation of alcohols.

Authors:  Mitchell J Schultz; Steven S Hamilton; David R Jensen; Matthew S Sigman
Journal:  J Org Chem       Date:  2005-04-29       Impact factor: 4.354

5.  Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation.

Authors:  Jessica M Hoover; Bradford L Ryland; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2013-01-31       Impact factor: 15.419

6.  CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides.

Authors:  Kengo Kataoka; Keiju Wachi; Xiongjie Jin; Kosuke Suzuki; Yusuke Sasano; Yoshiharu Iwabuchi; Jun-Ya Hasegawa; Noritaka Mizuno; Kazuya Yamaguchi
Journal:  Chem Sci       Date:  2018-05-07       Impact factor: 9.825

7.  Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water.

Authors:  Shi-Juan Liu; Miao Zhang; Rong Lu; Xiu-Ying Li; Guang-Bo Che
Journal:  Molecules       Date:  2018-07-27       Impact factor: 4.411

8.  An aerobic oxidation of alcohols into carbonyl synthons using bipyridyl-cinchona based palladium catalyst.

Authors:  Ravi Kumar Cheedarala; Ramasamy R Chidambaram; Ayyanar Siva; Jung Il Song
Journal:  RSC Adv       Date:  2021-10-06       Impact factor: 4.036

Review 9.  Directing transition metal-based oxygen-functionalization catalysis.

Authors:  Gracita M Tomboc; Yeji Park; Kwangyeol Lee; Kyoungsuk Jin
Journal:  Chem Sci       Date:  2021-06-23       Impact factor: 9.825
  9 in total

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