Literature DB >> 11975584

A study of the ionic liquid mediated microwave heating of organic solvents.

Nicholas E Leadbeater1, Hanna M Torenius.   

Abstract

The use of ionic liquids as aids for microwave heating of nonpolar solvents has been investigated. We show that hexane and toluene together with solvents such as THF and dioxane can be heated way above their boiling point in sealed vessels using a small quantity of an ionic liquid, thereby allowing them to be used as media for microwave-assisted chemistry. Using the appropriate ionic liquid, the heating can be performed with no contamination of the solvent. To show the applicability of the system, two test reactions have been successfully performed.

Entities:  

Year:  2002        PMID: 11975584     DOI: 10.1021/jo016297g

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  10 in total

1.  Microwave-assisted Mannich-type three-component reactions.

Authors:  Nicholas E Leadbeater; Hanna M Torenius; Heather Tye
Journal:  Mol Divers       Date:  2003       Impact factor: 2.943

2.  A rapid microwave protocol for Heck vinylation of aryl chlorides under air.

Authors:  Gopal K Datta; Karl S A Vallin; Mats Larhed
Journal:  Mol Divers       Date:  2003       Impact factor: 2.943

3.  Microwave-assisted protection of primary amines as 2,5-dimethylpyrroles and their orthogonal deprotection.

Authors:  Amit Walia; Soosung Kang; Richard B Silverman
Journal:  J Org Chem       Date:  2013-10-14       Impact factor: 4.354

Review 4.  Energy-Saving Pathways for Thermoelectric Nanomaterial Synthesis: Hydrothermal/Solvothermal, Microwave-Assisted, Solution-Based, and Powder Processing.

Authors:  Nagaraj Nandihalli; Duncan H Gregory; Takao Mori
Journal:  Adv Sci (Weinh)       Date:  2022-07-17       Impact factor: 17.521

5.  Rapid and efficient functionalized ionic liquid-catalyzed aldol condensation reactions associated with microwave irradiation.

Authors:  Chang Wang; Jing Liu; Wenguang Leng; Yanan Gao
Journal:  Int J Mol Sci       Date:  2014-01-17       Impact factor: 5.923

6.  A smart all-in-one theranostic platform for CT imaging guided tumor microwave thermotherapy based on IL@ZrO2 nanoparticles.

Authors:  Haitang Shi; Meng Niu; Longfei Tan; Tianlong Liu; Haibo Shao; Changhui Fu; Xiangling Ren; Tengchuang Ma; Jun Ren; Linlin Li; Huiyu Liu; Ke Xu; Jianxin Wang; Fangqiong Tang; Xianwei Meng
Journal:  Chem Sci       Date:  2015-05-29       Impact factor: 9.825

7.  Brønsted acidic ionic liquids for cellulose hydrolysis in an aqueous medium: structural effects on acidity and glucose yield.

Authors:  Shiori Suzuki; Yuko Takeoka; Masahiro Rikukawa; Masahiro Yoshizawa-Fujita
Journal:  RSC Adv       Date:  2018-04-18       Impact factor: 3.361

8.  Development of a microwave-assisted sustainable conversion of furfural hydrazones to functionalised phthalimides in ionic liquids.

Authors:  Valerija Karaluka; Kengo Murata; Shinto Masuda; Yuto Shiramatsu; Takuji Kawamoto; Helen C Hailes; Tom D Sheppard; Akio Kamimura
Journal:  RSC Adv       Date:  2018-06-20       Impact factor: 4.036

9.  Microwave-assisted method for simultaneous extraction and hydrolysis for determination of flavonol glycosides in Ginkgo foliage using Brönsted acidic ionic-liquid [HO(3)S(CH(2))(4)mim]HSO(4) aqueous solutions.

Authors:  Huanhuan Yao; Xinxuan Du; Lei Yang; Wenjie Wang; Fengjian Yang; Chunjian Zhao; Xiangdong Meng; Lin Zhang; Yuangang Zu
Journal:  Int J Mol Sci       Date:  2012-07-16       Impact factor: 6.208

10.  Influence of Polarity and Activation Energy in Microwave-Assisted Organic Synthesis (MAOS).

Authors:  Antonio M Rodríguez; Pilar Prieto; Antonio de la Hoz; Ángel Díaz-Ortiz; D Raúl Martín; José I García
Journal:  ChemistryOpen       Date:  2015-02-01       Impact factor: 2.911

  10 in total

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