| Literature DB >> 11975541 |
Kiyosei Takasu1, Sayaka Mizutani, Masataka Ihara.
Abstract
The intramoleculae Diels-Alder reaction of cyclohexenone having an unsaturated ester side chain afforded tricyclo[4.3.1.0(3,7)]decanone in both a regio- and stereoselective manner under TMSCl-NEt(3)-ZnBr(2) conditions. Unexpectedly, the regiochemical control was against the conventional orbital requirement.Entities:
Year: 2002 PMID： 11975541 DOI： 10.1021/jo016129o
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354