| Literature DB >> 11969859 |
Abstract
Recent Monte Carlo simulation studies of a Lennard-Jones fluid confined to a mesoscopic slit pore have reported evidence of "critical depletion" in the pore local number density near the liquid-vapor critical point. In this Brief Report we demonstrate that the observed depletion effect is in fact a simulation artifact arising from small systematic errors associated with the use of long range corrections for the potential truncation. Owing to the large near-critical compressibility, these errors lead to significant changes in the pore local number density. We suggest ways of avoiding similar problems in future studies of confined fluids.Year: 1999 PMID: 11969859 DOI: 10.1103/physreve.60.1081
Source DB: PubMed Journal: Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics ISSN: 1063-651X