Literature DB >> 11952349

Iron pentacarbonyl as a precursor for molecule-based magnets: formation of Fe[TCNE](2) (T(c) = 100 K) and Fe[TCNQ](2) (T(c) = 35 K) magnets.

Konstantyn I Pokhodnya1, Nate Petersen, Joel S Miller.   

Abstract

The reaction of tetracyanoethylene (TCNE) and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) with Fe(CO)(5) leads to formation of magnetically ordered materials of Fe[TCNE](2) (T(c) = 100 K) and Fe[TCNQ](2) (T(c) = 35 K) composition, respectively. In contrast, the reaction with 1,2-dichloro-5,6-dicyanobenzoquinone (DDQ) leads to a paramagnetic material.

Entities:  

Year:  2002        PMID： 11952349     DOI： 10.1021/ic011288b

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Flexible ε-Fe2O3-Terephthalate Thin-Film Magnets through ALD/MLD.

Authors:  Anish Philip; Janne-Petteri Niemelä; Girish C Tewari; Barbara Putz; Thomas Edward James Edwards; Mitsuru Itoh; Ivo Utke; Maarit Karppinen
Journal:  ACS Appl Mater Interfaces       Date:  2020-05-05       Impact factor: 9.229

2.  New aspect of photophysics of 7,7,8,8-tetracyanoquinodimethane and its solvated complexes: intra- vs. inter-molecular charge-transfer.

Authors:  Satoru Muramatsu; Nobumasa Chaki; Shin-Nosuke Kinoshita; Yoshiya Inokuchi; Manabu Abe; Toshifumi Iimori; Takayuki Ebata
Journal:  RSC Adv       Date:  2021-06-24       Impact factor: 4.036
  2 in total

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