Literature DB >> 11951981

Spiking of performance reference compounds in low density polyethylene and silicone passive water samplers.

Kees Booij1, Foppe Smedes, Evaline M van Weerlee.   

Abstract

A method for spiking performance reference compounds (PRCs) into low density polyethylene (LDPE) and silicone polymers is described. This method is based on equilibration of the polymers in aqueous/methanolic solutions of PRCs. Equilibration times range from minutes to hours for perdeuterated polyaromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) with a hydrophobicity in the range 3.9 < logKow < 7.7. Best results were obtained for methanol-water ratios of 80/20 (v/v). The method allows for the use of PRCs for in situ calibration of the uptake kinetics of these solvent-free sampling phases in a similar way as for semipermeable membrane devices (SPMDs).

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Year:  2002        PMID： 11951981     DOI： 10.1016/s0045-6535(01)00200-4

Source DB:  PubMed          Journal:  Chemosphere        ISSN： 0045-6535            Impact factor:   7.086


  26 in total

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10.  Ex situ determination of freely dissolved concentrations of hydrophobic organic chemicals in sediments and soils: basis for interpreting toxicity and assessing bioavailability, risks and remediation necessity.

Authors:  Michiel T O Jonker; Robert M Burgess; Upal Ghosh; Philip M Gschwend; Sarah E Hale; Rainer Lohmann; Michael J Lydy; Keith A Maruya; Danny Reible; Foppe Smedes
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