The development of lithium ion secondary batteries.

Lithium ion secondary batteries (LIBs) were successfully developed as battery systems with high volumetric and gravimetric energy densities, which were inherited from lithium secondary batteries (LSBs) with metallic lithium anodes. LSBs have several drawbacks, however, including poor cyclability and quick-charge rejection. The cell reaction in LIB is merely a topochemical one, namely the migration of lithium ions between positive and negative electroces. No chemical changes were observed in the two electrodes or in the electrolytes. This results in little chemical transformation of the active electrode materials and electrolytes, and thus, LIBs can overcome the weaknesses of LSBs; for example, LIBs show excellent cyclability and quick-charge acceptance. Many difficulties, however, were encountered during the course of development, including capacity fade during cycling and safety issues. This article is the story of the development of LIBs and it describes how the difficulties were surmounted. Copyright 2001 The Japan Chemical Journal Forum and John Wiley & Sons, Inc.