| Literature DB >> 11925155 |
Bin Wang1, Eric Rivard, Ian Manners.
Abstract
The phosphoranimine, Cl(3)P=NSiMe(3), was prepared using a new, high-yield (>80%), one-pot synthesis via oxidation of the chlorophosphine, Cl(2)PN(SiMe(3))(2) with SO(2)Cl(2) in ether. Cl(3)P=NSiMe(3) is a valuable monomeric precursor in the synthesis of well-defined polyphosphazenes.Entities:
Year: 2002 PMID: 11925155 DOI: 10.1021/ic011125n
Source DB: PubMed Journal: Inorg Chem ISSN: 0020-1669 Impact factor: 5.165