Literature DB >> 11925155

A new high-yield synthesis of Cl(3)P=NSiMe(3), a monomeric precursor for the controlled preparation of high molecular weight polyphosphazenes.

Bin Wang1, Eric Rivard, Ian Manners.   

Abstract

The phosphoranimine, Cl(3)P=NSiMe(3), was prepared using a new, high-yield (>80%), one-pot synthesis via oxidation of the chlorophosphine, Cl(2)PN(SiMe(3))(2) with SO(2)Cl(2) in ether. Cl(3)P=NSiMe(3) is a valuable monomeric precursor in the synthesis of well-defined polyphosphazenes.

Entities:  

Year:  2002        PMID: 11925155     DOI: 10.1021/ic011125n

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  13 in total

1.  Macromolecular Pt(IV) Prodrugs from Poly(organo)phosphazenes.

Authors:  Helena Henke; Kushtrim Kryeziu; Jelena Banfić; Sarah Theiner; Wilfried Körner; Oliver Brüggemann; Walter Berger; Bernhard K Keppler; Petra Heffeter; Ian Teasdale
Journal:  Macromol Biosci       Date:  2016-05-12       Impact factor: 4.979

2.  Nanodisco balls: control over surface versus core loading of diagnostically active nanocrystals into polymer nanoparticles.

Authors:  Peter Chhour; Nicolas Gallo; Rabee Cheheltani; Dewight Williams; Ajlan Al-Zaki; Taejong Paik; Jessica L Nichol; Zhicheng Tian; Pratap C Naha; Walter R Witschey; Harry R Allcock; Christopher B Murray; Andrew Tsourkas; David P Cormode
Journal:  ACS Nano       Date:  2014-09-09       Impact factor: 15.881

3.  Oxidation Responsive Polymers with a Triggered Degradation via Arylboronate Self-Immolative Motifs on a Polyphosphazene Backbone.

Authors:  Aitziber Iturmendi; Uwe Monkowius; Ian Teasdale
Journal:  ACS Macro Lett       Date:  2017-02-02       Impact factor: 6.903

4.  Degradable, Dendritic Polyols on a Branched Polyphosphazene Backbone.

Authors:  Anne Linhardt; Michael König; Aitziber Iturmendi; Helena Henke; Oliver Brüggemann; Ian Teasdale
Journal:  Ind Eng Chem Res       Date:  2018-02-23       Impact factor: 3.720

5.  Biodegradable Polyphosphazene Based Peptide-Polymer Hybrids.

Authors:  Anne Linhardt; Michael König; Wolfgang Schöfberger; Oliver Brüggemann; Alexander K Andrianov; Ian Teasdale
Journal:  Polymers (Basel)       Date:  2016-04-22       Impact factor: 4.329

6.  Cylindrical Micelles by the Self-Assembly of Crystalline-b-Coil Polyphosphazene-b-P2VP Block Copolymers. Stabilization of Gold Nanoparticles.

Authors:  Maria de Los Angeles Cortes; Raquel de la Campa; Maria Luisa Valenzuela; Carlos Díaz; Gabino A Carriedo; Alejandro Presa Soto
Journal:  Molecules       Date:  2019-05-07       Impact factor: 4.411

7.  Water-Soluble, Biocompatible Polyphosphazenes with Controllable and pH-Promoted Degradation Behavior.

Authors:  Sandra Wilfert; Aitziber Iturmendi; Wolfgang Schoefberger; Kushtrim Kryeziu; Petra Heffeter; Walter Berger; Oliver Brüggemann; Ian Teasdale
Journal:  J Polym Sci A Polym Chem       Date:  2014-01-15       Impact factor: 2.702

8.  Preparation of polyphosphazenes: a tutorial review.

Authors:  Sandra Rothemund; Ian Teasdale
Journal:  Chem Soc Rev       Date:  2016-06-17       Impact factor: 54.564

9.  Novel Approach for the Synthesis of Chlorophosphazene Cycles with a Defined Size via Controlled Cyclization of Linear Oligodichlorophosphazenes [Cl(PCl2=N)n-PCl3]+[PCl6].

Authors:  Mikhail Gorlov; Nikolay Bredov; Andrey Esin; Igor Sirotin; Mikhail Soldatov; Volodymyr Oberemok; Vyacheslav V Kireev
Journal:  Int J Mol Sci       Date:  2021-05-31       Impact factor: 5.923

10.  Polyphosphazene-Based Nanocarriers for the Release of Camptothecin and Epirubicin.

Authors:  Javier Pérez Quiñones; Cornelia Roschger; Aitziber Iturmendi; Helena Henke; Andreas Zierer; Carlos Peniche-Covas; Oliver Brüggemann
Journal:  Pharmaceutics       Date:  2022-01-11       Impact factor: 6.321

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