Literature DB >> 11869126

Microwave-assisted ketone-ketone rearrangement: an improved synthesis of 3-(4-alkoxyphenyl)-3- methylbutan-2-ones.

Geetha Gopalakrishnan1, Viswanathan Kasinath, N D Pradeep Singh.   

Abstract

[reaction: see text] A novel procedure for the preparation of 3-(4-alkoxyphenyl)-3-methylbutan-2-one in excellent yield is described via polymer-supported AlCl3-catalyzed rearrangement of 1-(4-ethoxyphenyl)-2,2-dimehtylpropan-1-one, followed by O-alkylation under microwave irradiation condition.

Entities:  

Year:  2002        PMID: 11869126     DOI: 10.1021/ol017265i

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

Review 1.  Advances in organic synthesis using polymer-supported reagents and scavengers under microwave irradiation.

Authors:  Sukanta Bhattacharyya
Journal:  Mol Divers       Date:  2005       Impact factor: 2.943

  1 in total

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