| Literature DB >> 11863940 |
M F Kropman1, H-K Nienhuys, H J Bakker.
Abstract
We present a study of the orientational dynamics of aqueous solvation shells of halogenic anions in bulk water solution with femtosecond two-color midinfrared spectroscopy. These orientational dynamics have time constants between 2.5 and 12 ps, depending on the type of anion and the temperature. We find that the solvation shell of the larger ion I- shows faster dynamics than that of the smaller ions Cl- and Br-.Entities:
Year: 2002 PMID： 11863940 DOI： 10.1103/PhysRevLett.88.077601
Source DB: PubMed Journal: Phys Rev Lett ISSN： 0031-9007 Impact factor: 9.161