Literature DB >> 11856050

Reactivity of stable trifluoroacetaldehyde hemiaminals. 2. Generation and synthetic potentialities of fluorinated iminiums.

Thierry Billard1, Bernard R Langlois.   

Abstract

Under Lewis acid activation, hemiaminals of trifluoroacetaldehyde and related (fluoroalkyl)aldehydes generate iminium species that can react with various nucleophiles to provide fluorinated amines.

Entities:  

Year:  2002        PMID： 11856050     DOI： 10.1021/jo016265t

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  5 in total

1.  Expanded substrate scope and improved reactivity of ether-forming cross-coupling reactions of organotrifluoroborates and acetals.

Authors:  Cam-Van T Vo; T Andrew Mitchell; Jeffrey W Bode
Journal:  J Am Chem Soc       Date:  2011-08-17       Impact factor: 15.419

2.  Functionalization of organotrifluoroborates: reductive amination.

Authors:  Gary A Molander; David J Cooper
Journal:  J Org Chem       Date:  2008-04-16       Impact factor: 4.354

Review 3.  Synthesis of Substituted α-Trifluoromethyl Piperidinic Derivatives.

Authors:  Sarah Rioton; Domingo Gomez Pardo; Janine Cossy
Journal:  Molecules       Date:  2017-03-19       Impact factor: 4.411

Review 4.  CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry.

Authors:  Anthony J Fernandes; Armen Panossian; Bastien Michelet; Agnès Martin-Mingot; Frédéric R Leroux; Sébastien Thibaudeau
Journal:  Beilstein J Org Chem       Date:  2021-02-03       Impact factor: 2.883

5.  Reactions of 3-aryl-1-(trifluoromethyl)prop-2-yn-1-iminium salts with 1,3-dienes and styrenes.

Authors:  Thomas Schneider; Michael Keim; Bianca Seitz; Gerhard Maas
Journal:  Beilstein J Org Chem       Date:  2020-08-24       Impact factor: 2.883
  5 in total

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