Literature DB >> 11829589

Indium(III) chloride-sodium borohydride system: a convenient radical reagent for an alternative to tributyltin hydride system.

Katsuyuki Inoue1, Akemi Sawada, Ikuya Shibata, Akio Baba.   

Abstract

The indium hydride generated from NaBH4 and InCl3, is a promising candidate of alternative to Bu3SnH. In particular, the catalytic performance of InCl3 in the dehalogenation of alkyl and aryl halides, intramolecular cyclization and intermolecular coupling reaction are noteworthy.

Entities:  

Year:  2002        PMID： 11829589     DOI： 10.1021/ja017537c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  EPR and pulsed ENDOR study of intermediates from reactions of aromatic azides with group 13 metal trichlorides.

Authors:  Giorgio Bencivenni; Riccardo Cesari; Daniele Nanni; Hassane El Mkami; John C Walton
Journal:  Beilstein J Org Chem       Date:  2010-08-09       Impact factor: 2.883

2.  Enantioselective synthesis of (-)-sclerophytin A by a stereoconvergent epoxide hydrolysis.

Authors:  Bin Wang; Armando P Ramirez; Justin J Slade; James P Morken
Journal:  J Am Chem Soc       Date:  2010-10-28       Impact factor: 15.419

3.  Efficient indium-mediated dehalogenation of aromatics in ionic liquid media.

Authors:  Alvaro F Cañete; Cristian O Salas; Flavia C Zacconi
Journal:  Molecules       Date:  2012-12-28       Impact factor: 4.411

4.  New total synthesis and structure confirmation of putative (+)-hyacinthacine C3 and (+)-5-epi-hyacinthacine C3.

Authors:  Lívia Dikošová; Barbora Otočková; Tomáš Malatinský; Jana Doháňošová; Mária Kopáčová; Anna Ďurinová; Lucie Smutná; František Trejtnar; Róbert Fischer
Journal:  RSC Adv       Date:  2021-09-24       Impact factor: 4.036

Review 5.  Main-Group Metal Complexes in Selective Bond Formations Through Radical Pathways.

Authors:  Crispin Lichtenberg
Journal:  Chemistry       Date:  2020-03-24       Impact factor: 5.236
  5 in total

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