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Literature DB >> 11820892

Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.

Yoshihisa Kobayashi¹, Nobuyuki Hayashi, Yoshito Kishi.

Abstract

The absolute configuration of acyclic secondary alcohols can be established from analysis of the chemical shift behaviors of the adjacent carbons in bidentate chiral solvents (R,R)- and (S,S)-1d as formulated in the boxed illustration.

Entities: Chemical

Mesh：

Substances：
Alcohols
Solvents

Year: 2002 PMID： 11820892 DOI： 10.1021/ol0171160

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

7 in total

1. INTEGRATED APPROACHES TO THE CONFIGURATIONAL ASSIGNMENT OF MARINE NATURAL PRODUCTS.

Authors: Tadeusz F Molinski; Brandon I Morinaka
Journal: Tetrahedron Date: 2012-11-18 Impact factor: 2.457

2. An ESI-MS method to determine yield and enantioselectivity in a single assay.

Authors: Maureen E Smith; Steven A Knolls; MyLe Thompson; Douglas S Masterson
Journal: J Am Soc Mass Spectrom Date: 2014-12-16 Impact factor: 3.109

3. Progressive-convergent elucidation of stereochemistry in complex polyols. The absolute configuration of (-)-sagittamide A.

Authors: Sarah C Lievens; Tadeusz F Molinski
Journal: J Am Chem Soc Date: 2006-09-13 Impact factor: 15.419

7. The robust, readily available cobalt(iii) trication [Co(NH₂CHPhCHPhNH₂)₃]³⁺ is a progenitor of broadly applicable chirality and prochirality sensing agents.

Authors: Quang H Luu; Kyle G Lewis; Anik Banerjee; Nattamai Bhuvanesh; John A Gladysz
Journal: Chem Sci Date: 2018-05-11 Impact factor: 9.825

7 in total

Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.

1. INTEGRATED APPROACHES TO THE CONFIGURATIONAL ASSIGNMENT OF MARINE NATURAL PRODUCTS.

2. An ESI-MS method to determine yield and enantioselectivity in a single assay.

3. Progressive-convergent elucidation of stereochemistry in complex polyols. The absolute configuration of (-)-sagittamide A.

4. Determination of absolute configuration using kinetic resolution catalysts.

5. Determination of absolute configuration of secondary alcohols using thin-layer chromatography.

Review 6. Recent advances and applications of experimental technologies in marine natural product research.

7. The robust, readily available cobalt(iii) trication [Co(NH₂CHPhCHPhNH₂)₃]³⁺ is a progenitor of broadly applicable chirality and prochirality sensing agents.

Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.

1. INTEGRATED APPROACHES TO THE CONFIGURATIONAL ASSIGNMENT OF MARINE NATURAL PRODUCTS.

2. An ESI-MS method to determine yield and enantioselectivity in a single assay.

3. Progressive-convergent elucidation of stereochemistry in complex polyols. The absolute configuration of (-)-sagittamide A.

4. Determination of absolute configuration using kinetic resolution catalysts.

5. Determination of absolute configuration of secondary alcohols using thin-layer chromatography.

Review 6. Recent advances and applications of experimental technologies in marine natural product research.

7. The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents.

7. The robust, readily available cobalt(iii) trication [Co(NH₂CHPhCHPhNH₂)₃]³⁺ is a progenitor of broadly applicable chirality and prochirality sensing agents.