Literature DB >> 11804475

A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N@C80.

Erick B Iezzi1, James C Duchamp, Kim Harich, Tom E Glass, Hon Man Lee, Marilyn M Olmstead, Alan L Balch, Harry C Dorn.   

Abstract

The reaction of Sc3N@C80 with 6,7-dimethoxyisochroman-3-one (13C labeled) provides the first functionalized derivative of the trimetallic nitride template (TNT) endohedral metallofullerene family. The reaction mixture is dominated by a single 13C labeled monoadduct product that was purified by HPLC. The 13C labeled monoadduct was characterized by 1H NMR, 13C NMR, and MALDI-TOF mass spectrometry. The proposed structure for this novel symmetric monoadduct is consistent with derivatization at the [5,6] ring juncture on the Sc3N@C80 cage.

Entities:  

Year:  2002        PMID： 11804475     DOI： 10.1021/ja0171005

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Photoinduced charge transfer and electrochemical properties of triphenylamine I(h)-Sc3N@C80 donor-acceptor conjugates.

Authors:  Julio R Pinzón; Diana C Gasca; Shankara G Sankaranarayanan; Giovanni Bottari; Tomás Torres; Dirk M Guldi; Luis Echegoyen
Journal:  J Am Chem Soc       Date:  2009-06-10       Impact factor: 15.419

2.  Biomedical activities of endohedral metallofullerene optimized for nanopharmaceutics.

Authors:  Jie Meng; Dong-liang Wang; Paul C Wang; Lee Jia; Chunying Chen; Xing-Jie Liang
Journal:  J Nanosci Nanotechnol       Date:  2010-12

3.  Determining the pharmacokinetics and long-term biodistribution of SiO2 nanoparticles in vivo using accelerator mass spectrometry.

Authors:  Michael A Malfatti; Heather A Palko; Edward A Kuhn; Kenneth W Turteltaub
Journal:  Nano Lett       Date:  2012-10-17       Impact factor: 11.189

4.  Chemically adjusting plasma temperature, energy, and reactivity (CAPTEAR) method using NOx and combustion for selective synthesis of Sc3N@C80 metallic nitride fullerenes.

Authors:  Steven Stevenson; M Corey Thompson; H Louie Coumbe; Mary A Mackey; Curtis E Coumbe; J Paige Phillips
Journal:  J Am Chem Soc       Date:  2007-12-01       Impact factor: 15.419

5.  Reliable charge assessment on encapsulated fragment for endohedral systems.

Authors:  A J Stasyuk; M Solà; A A Voityuk
Journal:  Sci Rep       Date:  2018-02-13       Impact factor: 4.379

Review 6.  Medicinal applications of fullerenes.

Authors:  Rania Bakry; Rainer M Vallant; Muhammad Najam-ul-Haq; Matthias Rainer; Zoltan Szabo; Christian W Huck; Günther K Bonn
Journal:  Int J Nanomedicine       Date:  2007

7.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236

8.  Synthesis and characterization of carbene derivatives of Th@C 3v(8)-C82 and U@C 2v(9)-C82: exceptional chemical properties induced by strong actinide-carbon cage interaction.

Authors:  Xinye Liu; Bo Li; Wei Yang; Yang-Rong Yao; Le Yang; Jiaxin Zhuang; Xiaomeng Li; Peng Jin; Ning Chen
Journal:  Chem Sci       Date:  2020-12-21       Impact factor: 9.825
  8 in total

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