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Literature DB >> 11784206

Formation of aryl-nitrogen, aryl-oxygen, and aryl-carbon bonds using well-defined copper(I)-based catalysts.

R K Gujadhur¹, C G Bates, D Venkataraman.

Abstract

We report mild synthetic protocols for the formation of aryl-carbon, aryl-nitrogen, and aryl-oxygen bonds based on soluble, well-defined copper(I) catalysts. These protocols do not require the use of palladium and/or expensive ligands. [structure: see text]

Entities: Chemical

Year: 2001 PMID： 11784206 DOI： 10.1021/ol0170105

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

19 in total

1. Base-mediated stereospecific synthesis of aryloxy and amino substituted ethyl acrylates.

Authors: M Shahjahan Kabir; Ojas A Namjoshi; Ranjit Verma; Michael Lorenz; V V N Phani Babu Tiruveedhula; Aaron Monte; Steven H Bertz; Alan W Schwabacher; James M Cook
Journal: J Org Chem Date: 2011-11-28 Impact factor: 4.354

2. Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides.

Authors: Jesse W Tye; Zhiqiang Weng; Adam M Johns; Christopher D Incarvito; John F Hartwig
Journal: J Am Chem Soc Date: 2008-07-03 Impact factor: 15.419

3. Palladium-catalyzed synthesis of N-vinyl pyrroles and indoles.

Authors: Mohammad Movassaghi; Alison E Ondrus
Journal: J Org Chem Date: 2005-10-14 Impact factor: 4.354

4. Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions.

Authors: Gavin O Jones; Peng Liu; K N Houk; Stephen L Buchwald
Journal: J Am Chem Soc Date: 2010-05-05 Impact factor: 15.419

5. A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.

Authors: Luca Salvi; Nicole R Davis; Siraj Z Ali; Stephen L Buchwald
Journal: Org Lett Date: 2011-12-19 Impact factor: 6.005

6. Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic Cu^I Intermediates.

Authors: Ramesh Giri; Andrew Brusoe; Konstantin Troshin; Justin Y Wang; Marc Font; John F Hartwig
Journal: J Am Chem Soc Date: 2018-01-05 Impact factor: 15.419

Formation of aryl-nitrogen, aryl-oxygen, and aryl-carbon bonds using well-defined copper(I)-based catalysts.

1. Base-mediated stereospecific synthesis of aryloxy and amino substituted ethyl acrylates.

2. Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides.

3. Palladium-catalyzed synthesis of N-vinyl pyrroles and indoles.

4. Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions.

5. A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions.

6. Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic Cu^I Intermediates.

7. C-O bond Formation in a Microfluidic Reactor: High Yield S_NAr Substitution of Heteroaryl Chlorides.

8. Copper(I) phenoxide complexes in the etherification of aryl halides.

9. Mechanistic studies on the copper-catalyzed N-arylation of amides.

10. Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides.