Literature DB >> 11784196

Unusual influence of substituents on ring-opening metathesis reactions.

D L Wright1, L C Usher, M Estrella-Jimenez.   

Abstract

The ring-opening cross-metathesis of oxabicyclo[3.2.1]octene derivatives provides a convenient method for preparing differentially substituted 4-pyrones. The major competing reaction is the ring-opening metathesis polymerization of the bridged olefin. Studies on this reaction have shown that substituents on the bicyclic alkene can have a dramatic influence on the competing reactions. [reaction: see text]

Entities:  

Year:  2001        PMID: 11784196     DOI: 10.1021/ol016936+

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Manipulating micellar environments for enhancing transition metal-catalyzed cross-couplings in water at room temperature.

Authors:  Bruce H Lipshutz; Subir Ghorai; Wendy Wen Yi Leong; Benjamin R Taft; Daniel V Krogstad
Journal:  J Org Chem       Date:  2011-05-19       Impact factor: 4.354

2.  Synthesis of functionalizable and degradable polymers by ring-opening metathesis polymerization.

Authors:  Joshua M Fishman; Laura L Kiessling
Journal:  Angew Chem Int Ed Engl       Date:  2013-04-08       Impact factor: 15.336

3.  The tandem ring opening/ring closing metathesis route to oxaspirocycles: an approach to phelligridin G.

Authors:  Harold D Cooper; Dennis L Wright
Journal:  Molecules       Date:  2013-02-21       Impact factor: 4.411

  3 in total

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