Literature DB >> 11784195

Nucleophilic trifluoromethylation using trifluoromethyl iodide. A new and simple alternative for the trifluoromethylation of aldehydes and ketones.

S Aït-Mohand1, N Takechi, M Médebielle, W R Dolbier.   

Abstract

A novel method for nucleophilic trifluoromethylation of aldehydes and ketones, based on photoinduced reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE), is presented. [reaction: see text]

Entities:  

Year:  2001        PMID： 11784195     DOI： 10.1021/ol016933x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Aryl dechlorination and defluorination with an organic super-photoreductant.

Authors:  Felix Glaser; Christopher B Larsen; Christoph Kerzig; Oliver S Wenger
Journal:  Photochem Photobiol Sci       Date:  2020-06-26       Impact factor: 3.982

2.  Nucleophilic trifluoromethylation of carbonyl compounds: trifluoroacetaldehyde hydrate as a trifluoromethyl source.

Authors:  G K Surya Prakash; Zhe Zhang; Fang Wang; Socrates Munoz; George A Olah
Journal:  J Org Chem       Date:  2013-02-28       Impact factor: 4.354

3.  Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis.

Authors:  David A Nagib; Mark E Scott; David W C MacMillan
Journal:  J Am Chem Soc       Date:  2009-08-12       Impact factor: 15.419

4.  Discovery and development of organic super-electron-donors.

Authors:  John A Murphy
Journal:  J Org Chem       Date:  2014-03-25       Impact factor: 4.354

5.  Reduction of arenediazonium salts by tetrakis(dimethylamino)ethylene (TDAE): efficient formation of products derived from aryl radicals.

Authors:  Mohan Mahesh; John A Murphy; Franck LeStrat; Hans Peter Wessel
Journal:  Beilstein J Org Chem       Date:  2009-01-12       Impact factor: 2.883

6.  Enantioselective nucleophilic difluoromethylation of aromatic aldehydes with Me3SiCF2SO2Ph and PhSO2CF2H reagents catalyzed by chiral quaternary ammonium salts.

Authors:  Chuanfa Ni; Fang Wang; Jinbo Hu
Journal:  Beilstein J Org Chem       Date:  2008-06-26       Impact factor: 2.883
  6 in total

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