Literature DB >> 11777467

Regioselective organocadmium alkylations of substituted quinones.

Aaron Aponick1, Ryan S Buzdygon, Robert J Tomko, Aleem N Fazal, Ellen L Shughart, Danielle M McMaster, Michael C Myers, William H Pitcock, Carl T Wigal.   

Abstract

A series of substituted quinones was alkylated with diethylcadmium. Regiochemistry of addition shifted from quinol formation to conjugate addition as a function of the steric and electronic effects of the substituents.

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Year:  2002        PMID: 11777467     DOI: 10.1021/jo016071d

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  TESOTf-induced rearrangement of quinols. Efficient construction of the fully functionalized carbon skeleton of the griseusins by a divergent-reconvergent approach.

Authors:  Kathlyn A Parker; Thomas L Mindt; Yung-hyo Koh
Journal:  Org Lett       Date:  2006-04-27       Impact factor: 6.005

  1 in total

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