| Literature DB >> 11772092 |
John P Morgan1, Christie Morrill, Robert H Grubbs.
Abstract
[reaction: see text] The selective ring opening cross metathesis of 1,5-cyclooctadiene and trisubstituted cycloolefins with acroyl species is described. The ring-opened products contain electronically differentiated olefins suitable for additional metathesis reactions. Trisubstituted cycloolefins open regioselectively, placing the acroyl cap on the less-substituted terminus.Entities:
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Year: 2002 PMID： 11772092 DOI： 10.1021/ol016918s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005