Literature DB >> 11754290

Synthesis, structural characterization, and photophysics of dinuclear gold(II) complexes [(Au(dppn)Br)(2)](PF(6))(2) and [(Au(dppn)I)(2)](PF(6))(2) with an unsupported Au(II)-Au(II) Bond.

V W Yam1, C K Li, C L Chan, K K Cheung.   

Abstract

A series of novel dinuclear gold(II) complexes having an unsupported Au(II)-Au(II) bond with well-defined oxidation state at the gold center were synthesized. Red shifts in both the low-energy absorption and emission bands were observed upon increasing the donor ability of the coordinated halogen atoms.

Entities:  

Year:  2001        PMID： 11754290     DOI： 10.1021/ic010744t

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes.

Authors:  Ekaterina Tkatchouk; Neal P Mankad; Diego Benitez; William A Goddard; F Dean Toste
Journal:  J Am Chem Soc       Date:  2011-08-23       Impact factor: 15.419

2.  Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF2 )n Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation.

Authors:  Alejandro Portugués; Delia Bautista; Juan Gil-Rubio
Journal:  Chemistry       Date:  2021-09-29       Impact factor: 5.020

Review 3.  Excimer and Exciplex Formation in Gold(I) Complexes Preconditioned by Aurophilic Interactions.

Authors:  Hubert Schmidbaur; Helgard G Raubenheimer
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-08       Impact factor: 16.823
  3 in total

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