Literature DB >> 11735596

Coupling of alkynylTMS derivatives with vinylic iodides. An efficient route to 1,3-enynes and dienes.

J A Marshall1, H R Chobanian, M M Yanik.   

Abstract

[reaction: see text] CuCl-promoted coupling of alkynylTMS derivatives with vinyl iodides leads to 1,3-enynes in high yield. Enynes prepared from homopropargylic alcohols undergo intramolecular hydrosilylation and subsequent silyl cleavage with TBAF to afford 1,3-dienes.

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Year:  2001        PMID： 11735596     DOI： 10.1021/ol016899m

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Design and Synthesis of a New Class of Twin-Chain Amphiphiles for Self-Assembled Monolayer-based Electrochemical Biosensor Applications.

Authors:  Thomas J Fisher; Socrates Jose P Cañete; Rebecca Y Lai; Patrick H Dussault
Journal:  European J Org Chem       Date:  2013-06-01

2.  Synthesis and spectral properties of cholesterol- and FTY720-containing boron dipyrromethene dyes.

Authors:  Zaiguo Li; Robert Bittman
Journal:  J Org Chem       Date:  2007-10-03       Impact factor: 4.354

3.  Site-Selective Suzuki-Miyaura and Sonogashira Cross Coupling Reactions of the Bis(triflate) of 2,4'-Bis(hydroxy)diphenyl Sulfone.

Authors:  Rasheed Ahmad Khera; Asad Ali; Munawar Hussain; Muhammad Farooq Ibad; Alexander Villinger; Peter Langer
Journal:  ChemCatChem       Date:  2012-02-01       Impact factor: 5.686
  3 in total

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